1st Division Hamilton Accies and Motherwell's SPL rivals Aberdeen have already been put to the sword by Billy Stark's men and they will be looking to add Maurice Malpas' Steelmen to the list.
The game will be played on either the 19th or 20th September at Hampden Park, full draw as follows:
Hibs -vs- Gretna
QUEEN'S PARK -vs- Motherwell
Inverness CT -vs- Falkirk
St Johnstone -vs- Dundee United
Kilmarnock -vs- Livingston
Dunfermline -vs- Rangers
Celtic -vs- St Mirren
Alloa -vs- Hearts